It should be centered. (Was the Mavic wheel centered? then it's a dishing problem with the Velocity wheel.)
Try mounting the back wheel reversed, with the cogs on the non-drive side. Is it off center the other direction?
If off center the other direction, the wheel isn't dished correctly to be centered. A bike shop can fix this easily.
If still off to the non-drive side, then the frame is out of alignment. I had a bike like that, with carbon stays, so it couldn't be bent back to center like a steel bike. I used a rounded jeweler file to "carefully, slowly" remove a slight amount of the aluminum dropout on the shorter side to allow the wheel to move back to the center. It only takes a paper thin amount of change at the dropout to noticeably move the tire.
I've seen quick releases dig into the softer aluminum dropout, causing the wheel to lock off center. If you push the wheel into the dropouts, and it's centered, then gets off when locked down, that might be the problem. Smoothing the surface of the dropout can fix this.
If you have carbon dropouts, I don't know if these fixes would be a good idea at all.